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Lithium potassium acetyl phosphate

SIGMA/A0262 - high-energy phosphate donor

Synonym: Acetyl phosphate lithium potassium salt

CAS Number: 94249-01-1
Empirical Formula (Hill Notation): C2H3KLiO5P
Molecular Weight: 184.06
EC Number: 304-378-0
MDL Number: MFCD00002134
Linear Formula: CH3COOP(O)(OK)(OLi)
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-A0262-500MG 500 mg
$203.00
1/EA
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45-A0262-1G 1 g
$298.00
1/EA
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45-A0262-5G 5 g
$1060.00
1/EA
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assay ≥85% (elemental analysis)
form powder
InChI 1S/C2H5O5P.K.Li/c1-2(3)7-8(4,5)6;;/h1H3,(H2,4,5,6);;/q;2*+1/p-2
InChI key RLQMPLKXFIXRCV-UHFFFAOYSA-L
mp >300 °C (lit.)
Quality Level 200 
SMILES string [Li+].[K+].CC(=O)OP([O-])([O-])=O
solubility water: 25 mg/mL, clear, colorless
storage temp. −20°C
Application: Lithium potassium acetyl phosphate:
• has been used as a substrate for CpxR (transcription factor) in x-ray crystallography to soak CpxR receiver domain (CpxRRD) crystals to obtain the phosphorylated form
• may be used as a phosphate (P) donor in a study to screen a wide range of natural and synthetic organic phosphate donors with several enzymes on various hydroxyl?compounds for the improved enzymatic synthesis of phosphate monoesters
• has been used to set up premixA for in vitro translation reaction

Biochem/physiol Actions: Lithium potassium acetyl phosphate is commonly used as the source for acetyl phosphate. So acetyl phosphate can be used as a suitable alternative to replace inorganic oligophosphates in phosphatase-catalyzed transphosphorylation to reduce inorganic monophosphate by-product formation.
Purity ≥85% (elemental analysis)
mp >300 °C (lit.)
Storage Temp. −20°C
UNSPSC 12352204

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