tert-Butyl methyl ether
SIGALD/443808 - ACS reagent, ≥99.0%
Synonym: MTBE; Methyl tert-butyl ether
CAS Number: 1634-04-4
Empirical Formula (Hill Notation): C5H12O
Molecular Weight: 88.15
EC Number: 216-653-1
MDL Number: MFCD00008812
Linear Formula: (CH3)3COCH3
Product Type: Chemical
| application(s) | microbiology |
| assay | ≥99.0% |
| autoignition temp. | 705 °F |
| bp | 55-56 °C (lit.) |
| color | APHA: ≤10 |
| density | 0.74 g/mL at 25 °C (lit.) |
| evapn. residue | ≤0.001% |
| expl. lim. | 15.1 % |
| form | liquid |
| grade | ACS reagent |
| impurities | ≤0.05% water |
| <1 ppm H2O2 | |
| InChI | 1S/C5H12O/c1-5(2,3)6-4/h1 |
| InChI key | BZLVMXJERCGZMT-UHFFFAOYSA |
| mp | -110 °C |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | COC(C)(C)C |
| vapor density | 3.1 (vs air) |
| vapor pressure | 4.05 psi |
| Application: | tert-Butyl methyl ether (methyl tert-butyl ether, MTBE) may be used: • As sole carbon and energy source in a mixed microbial consortium. • To extract lipids from biological fluids for shotgun profiling. • To synthesize fatty acid methyl esters (FAMEs) and glycerol tert-butyl ether by transesterification of canola oil in the absence of catalyst under supercritical condition. |
| General description: | tert-Butyl methyl ether (methyl tert-butyl ether, MTBE) is a gasoline additive. Its oxidative degradation by propane-oxidizing bacterial strains has been tested. Kinetics of its heat-mediated biodegradation has been investigated under various reaction conditions. Its biodegradation followed a pseudo-first-order decay model and its pseudo-first-order rate constants were evaluated. Its extraction from water has been proposed by employing an organic polymeric compound, Nafion. MTBE can be synthesized by acid-catalyzed reaction between methanol and isobutene. A study suggests that the addition of MTBE increases the number of active sites during polymerization of propene by stopped-flow method. This solvent meets ACS (American Chemical Society) specifications and can be used for processes requiring strict quality conditions such as analytical testing. |
| Packaging: | 1, 6×1 L in Sure/Seal™ |
| Packaging: | 18, 200 L in steel drum |
| Packaging: | 2.5, 4×2.5, 4×4 L in glass bottle |
| Packaging: | 500 mL in Sure/Seal™ |
| Symbol |   GHS02,GHS07 |
| Signal word | Danger |
| Hazard statements | H225 - H315 |
| Precautionary statements | P210 - P233 - P240 - P241 - P242 - P303 + P361 + P353 |
| Hazard Codes | F,Xi |
| Risk Statements | 11-38 |
| Safety Statements | 9-16-24 |
| RIDADR | UN 2398 3 / PGII |
| WGK Germany | WGK 1 |
| Flash Point(F) | -18.4 °F - closed cup |
| Flash Point(C) | -28 °C - closed cup |
| Purity | ≥99.0% |
| bp | 55-56 °C (lit.) |
| mp | -110 °C |
| Density | 0.74 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352112 |