Titanium(IV) chloride solution
SIGALD/249866 - 1.0 M in methylene chloride
Synonym: Titanium tetrachloride
CAS Number: 7550-45-0
Empirical Formula (Hill Notation): Cl4Ti
Molecular Weight: 189.68
MDL Number: MFCD00011267
Linear Formula: TiCl4
Product Type: Chemical
| concentration | 0.95-1.10 M NaOH (titration) |
| 1.0 M in methylene chloride | |
| density | 1.365 g/mL at 25 °C |
| form | liquid |
| InChI | 1S/4ClH.Ti/h4*1H;/q;;;;+4 |
| InChI key | XJDNKRIXUMDJCW-UHFFFAOYSA |
| Quality Level | 100 ![]() |
| reaction suitability | reagent type: catalyst core: titanium |
| SMILES string | Cl[Ti](Cl)(Cl)Cl |
| vapor pressure | 24.09 psi ( 55 °C) |
| 6.93 psi ( 20 °C) |
| Application: | Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines. |
| General description: | Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide. |
| Packaging: | 100, 4×100, 800 mL in Sure/Seal™ |
| Symbol | ![]() ![]() GHS05,GHS06,GHS08 |
| Signal word | Danger |
| Hazard statements | H314 - H331 - H336 - H351 |
| Precautionary statements | P201 - P280 - P303 + P361 + P353 - P304 + P340 + P311 - P305 + P351 + P338 + P310 - P308 + P313 |
| Hazard Codes | C |
| Risk Statements | 14-34-37-40-67 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN3289 - class 6.1 - PG 2 - acidic - Toxic liquid, corrosive, in |
| WGK Germany | WGK 2 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Supplemental Hazard Statements | EUH014 |
| Density | 1.365 g/mL at 25 °C |
| UNSPSC | 12352300 |




