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UltraCat

SIAL/901814 - ≥95%

Synonym: Bis(1-(2,6-diethylphenyl)-3,5,5-trimethyl-3-phenylpyrrolidin-2-ylidene)dichloro(3-phenyl-1H-inden-1-ylidene)ruthenium(II)

Empirical Formula (Hill Notation): C61H68Cl2N2Ru · CH3NO2
Molecular Weight: 1062.22
Linear Formula: C61H68Cl2N2Ru · CH3NO2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-901814-100MG 100 mg
 $116.00
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assay ≥95%
form powder
InChI 1S/2C23H30N.C15H10.CH3NO2.2ClH.Ru/c2*1-6-18-12-11-13-19(7-2)21(18)24-17-23(5,16-22(24,3)4)20-14-9-8-10-15-20;1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;1-2(3)4;;;/h2*8-15,17H,6-7,16H2,1-5H3;1-9,11H;1H3;2*1H;/q;;;;;;+2/p-2
InChI key YAAAJNYWUUZECH-UHFFFAOYSA-L
mp >300 °C
reaction suitability core: ruthenium
  reagent type: catalyst
SMILES string Cl[Ru](Cl)(C1N(C2=C(CC)C=CC=C2CC)C(C)(C)CC1(C)C3=CC=CC=C3)(C4N(C5=C(CC)C=CC=C5CC)C(C)(C)CC4(C6=CC=CC=C6)C)=C7C8=CC=CC=C8C(C9=CC=CC=C9)=C7.C[N+]([O-])=O
storage temp. 2-8°C
Application: UltraCat is excellent for CM (cross metathesis) of terminal, type 1 olefins and excellent for ethenolysis. The catalyst is also very good for mRCM (macrocyclic ring-closing metathesis) and RCM (ring closing metathesis) leading to small/medium rings. Reactions can be run at 40 to 85 °C. The following reaction solvents are compatible: toluene, ethyl acetate, dimethylcarbonate, CPME (cyclopentyl methyl ether), and neat substrate.

Learn more about our metathesis catalysts 
Legal Information: Sold in collaboration with Apeiron Synthesis, Inc. Research quantities are 100 g / customer / year. For quantities that exceed the research limit, please contact the supplier at www.apeiron-synthesis.com.
WO 2017/055945
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥95%
mp >300 °C
Storage Temp. 2-8°C
UNSPSC 12352101

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