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nitro-Grela

SIAL/901755 - ≥95%

Synonym: (1,3-Dimesitylimidazolidin-2-ylidene)dichloro(2-isopropoxy-5-nitrobenzylidene)ruthenium(II)

CAS Number: 502964-52-5
Empirical Formula (Hill Notation): C31H37Cl2N3O3Ru
Molecular Weight: 671.62
MDL Number: MFCD28411645
Linear Formula: C31H37Cl2N3O3Ru
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-901755-100MG 100 mg
 $96.60
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 901755-100MG.

 

assay ≥95%
form powder
InChI 1S/C21H26N2.C10H11NO3.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-7(2)14-10-5-4-9(11(12)13)6-8(10)3;;;/h9-12H,7-8H2,1-6H3;3-7H,1-2H3;2*1H;/q;;;;+2/p-2
InChI key RQQSRSPQJIAORC-UHFFFAOYSA-L
mp >300 °C
reaction suitability core: ruthenium
  reagent type: catalyst
SMILES string [Ru+2](=C2N(CCN2c4c(cc(cc4C)C)C)c3c(cc(cc3C)C)C)=Cc1c(ccc(c1)[N+](=O)[O-])OC(C)C.[Cl-].[Cl-]
storage temp. 2-8°C
Application: nitro-Grela is a universal catalyst which provides good results in a wide spectrum of olefin metathesis transformations. The catalyst provides high efficiency in cross metathesis (CM) reactions between type 1 olefins and an electron deficient partner. The catalyst is very good for CM of disubstituted internal olefins.
Legal Information: Sold in collaboration with Apeiron Synthesis, Inc. Research quantities are 100 g / customer / year. For quantities that exceed the research limit, please contact the supplier at www.apeiron-synthesis.com.
PCT/EP2003/011222
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥95%
mp >300 °C
Storage Temp. 2-8°C
UNSPSC 12161600

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