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4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl

SIAL/00375 - purum, ≥98.0% (HPLC)

CAS Number: 14691-89-5
Empirical Formula (Hill Notation): C11H21N2O2
Molecular Weight: 213.30
EC Number: 423-840-3
MDL Number: MFCD00043593
Linear Formula: C11H21N2O2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-00375-1G 1 g
 $77.80
1/EA		 Add To Favorites
45-00375-5G 5 g
 $317.00
1/EA		 Add To Favorites
12 Principles of Green Chemistry: Principle 1—Waste Prevention.  This product has a smaller environmental footprint through reduction of waste in the manufacturing process.
12 Principles of Green Chemistry: Principle 5—Safer Solvents and Auxiliaries. This product utilizes reduced volumes of auxiliary substances that are less hazardous.
12 Principles of Green Chemistry: Principle 12—Inherently Safer Chemistry for Accident Prevention.  This product utilizes safer chemistry to minimize the potential for chemical accidents, including releases, explosions and fires.

 

assay ≥98.0% (HPLC)
grade purum
greener alternative category Re-engineered 
greener alternative product characteristics Waste Prevention
Safer Solvents and Auxiliaries
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry .
greener alternative product score old score: 9
new score: 8
Find out more about DOZN™ Scoring 
InChI 1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
InChI key UXBLSWOMIHTQPH-UHFFFAOYSA-N
mp 143-145 °C (lit.)
  143-146 °C
Quality Level 200 
SMILES string CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
storage temp. 2-8°C
Application: 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.
General description: 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.
Other Notes: New oxidant for the mild oxidation of alcohols to carbonyls
Symbol GHS07  GHS07
Signal word Warning
Hazard statements H302
Precautionary statements P264 - P270 - P301 + P312 + P330 - P501
Hazard Codes Xn
Risk Statements 22
Safety Statements 22
RIDADR NONH for all modes of transport
WGK Germany WGK 1
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥98.0% (HPLC)
mp 143-145 °C (lit.); 143-146 °C
Storage Temp. 2-8°C
UNSPSC 12352005

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