N,N-Dimethylhydrazine
ALDRICH/D161608 - 98%
Synonym: 1,1-
CAS Number: 57-14-7
Empirical Formula (Hill Notation): C2H8N2
Molecular Weight: 60.10
EC Number: 200-316-0
MDL Number: MFCD00007628
Linear Formula: (CH3)2NNH2
Product Type: Chemical
FT-NMR Spectra for 1,1-Dimethylhydrazine.
FT-IR Spectra for 1,1-Dimethylhydrazine.
| assay | 98% |
| autoignition temp. | 478 °F |
| bp | 60-62 °C (lit.) |
| density | 0.79 g/mL at 20 °C (lit.) |
| expl. lim. | 95 % |
| form | liquid |
| InChI | 1S/C2H8N2/c1-4(2)3/h3H2,1 |
| InChI key | RHUYHJGZWVXEHW-UHFFFAOYSA |
| refractive index | n |
| SMILES string | CN(C)N |
| storage temp. | 2-8°C |
| vapor density | 1.94 (vs air) |
| vapor pressure | 103 mmHg ( 20 °C) |
| Application: | N,N-Dimethylhydrazine can react with: • β-Naphthol via radical amination to form 1-amino-2-naphthol. • 2-Chloro- and 2,2-dichloro-(bromo)vinyl ketones via regioselective heterocyclization to form 3-substituted 1-methyl(5-halo)pyrazoles • Terminal alkynes in the presence of TpRuCl(PPh3)2 (Tp = tris(pyrazolyl)borate) to form nitriles. N,N-Dimethylhydrazine along with ferric chloride hexahydrate forms an effective reduction system for: • Synthesizing DNA binding pyrrolo[2,1-c][1,4]benzodiazepine (PBD) imines via reductive cyclization of the corresponding nitro aldehyde. • Transforming a variety of nitroarenes and azido compounds into the corresponding anilines and amino compounds, respectively. |
| Biochem/physiol Actions: | Lung and colon tumor initiator in experimental animal model. |
| Packaging: | 5, 100, 500 g in glass bottle |
| Symbol |      GHS02,GHS05,GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H225 - H301 + H311 + H331 - H314 - H335 - H350 - H411 |
| Precautionary statements | P201 - P210 - P280 - P301 + P310 + P330 - P303 + P361 + P353 - P305 + P351 + P338 |
| Hazard Codes | F,T,N |
| Risk Statements | 45-11-23/24/25-34-37-51/53 |
| Safety Statements | 53-36/37-45-61 |
| RIDADR | UN1163 - class 6.1 - PG 1 - Dimethylhydrazine, unsymmetrical |
| WGK Germany | WGK 3 |
| Flash Point(F) | 14.0 °F - closed cup |
| Flash Point(C) | -10 °C - closed cup |
| Purity | 98% |
| bp | 60-62 °C (lit.) |
| Density | 0.79 g/mL at 20 °C (lit.) |
| Refractive Index | n |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352100 |