Dimethyl acetylenedicarboxylate
ALDRICH/D138401 - 95%
Synonym: Dimethyl 2-butynedioate
CAS Number: 762-42-5
Empirical Formula (Hill Notation): C6H6O4
Molecular Weight: 142.11
EC Number: 212-098-4
MDL Number: MFCD00008456
Linear Formula: CH3OCOC≡CCO2CH3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: D138401-5G.
| assay | 95% |
| bp | 95-98 °C/19 mmHg (lit.) |
| density | 1.156 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C6H6O4/c1-9-5(7)3-4-6( |
| InChI key | VHILMKFSCRWWIJ-UHFFFAOYSA |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | COC(=O)C#CC(=O)OC |
| Application: | Versatile dienophile used in Diels-Alder reactions. |
| General description: | Dimethyl acetylenedicarboxylate (DMAD) is an ester utilized as a dienophile and a dipolarophile in cycloaddition reactions. |
| Packaging: | 5, 25 g in glass bottle |
| Symbol |   GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H302 - H314 |
| Precautionary statements | P270 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 23-26-27-36/37/39-45 |
| RIDADR | UN 3265 8 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 186.8 °F - closed cup |
| Flash Point(C) | 86 °C - closed cup |
| Purity | 95% |
| bp | 95-98 °C/19 mmHg (lit.) |
| Density | 1.156 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |