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Azidobenzene solution

ALDRICH/778583 - ~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)

Synonym: Phenyl azide solution

CAS Number: 622-37-7
Empirical Formula (Hill Notation): C6H5N3
Molecular Weight: 119.12
MDL Number: MFCD00040895
Linear Formula: C6H5N3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-778583-10ML 10 mL
 $164.00
1/EA		 Add To Favorites
45-778583-50ML 50 mL
 $737.00
1/EA		 Add To Favorites
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

 

assay ≥95.0% (HPLC)
concentration ~0.5 M in 2-methyltetrahydrofuran
form liquid
greener alternative category Aligned ,  
greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry .
impurities ≤2.0% water
InChI 1S/C6H5N3/c7-9-8-6-4-2-1-3-5-6/h1-5H
InChI key CTRLRINCMYICJO-UHFFFAOYSA-N
Quality Level 100 
SMILES string [N-]=[N+]=Nc1ccccc1
storage temp. −20°C
sustainability Greener Alternative Product
Application: Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry 
General description: Azidobenzene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.
General description: Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.
Purity ≥95.0% (HPLC)
Storage Temp. −20°C
UNSPSC 12352200

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