Zinc difluoromethanesulfinate
ALDRICH/767840 - 95%
Synonym: Bis(((difluoromethyl)
CAS Number: 1355729-38-2
Empirical Formula (Hill Notation): C2H2F4O4S2Zn
Molecular Weight: 295.55
MDL Number: MFCD23134675
Linear Formula: C2H2F4O4S2Zn
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 767840-100MG.
Baran Diversinate for Late-Stage Functionalization
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 767840-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 767840-10G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 767840-1G
| assay | 95% |
| form | solid |
| functional group | fluoro |
| sulfinic acid | |
| InChI | 1S/2CH2F2O2S.Zn/c2*2-1(3) |
| InChI key | UGEYAPVLXKEKMP-UHFFFAOYSA |
| Quality Level | 100  |
| reaction suitability | reaction type: C-C Bond Formation |
| reaction type: Fluorinations | |
| reagent type: catalyst reaction type: C-H Activation |
|
| reagent type: diversification reagent | |
| SMILES string | FC(F)S(=O)O[Zn]OS(=O)C(F) |
| storage temp. | 2-8°C |
| Application: | Zinc difluoromethanesulfinate (DFMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.† Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles  DFMS is a new reagent for direct difluoromethylation of organic substrates via a radical process. This mild, operationally simple, chemoselective, and scalable difluoromethylation method is compatible with a range of nitrogen-containing heteroarene substrates of varying complexity as well as select classes of conjugated p−systems and thiols.† A New Reagent for Direct Difluoromethylation Learn More at the Professor and Product Portal of Professor Phil S. Baran. |
| General description: | Material is complexed with up to 1 equivalent of ZnCl2 |
| General description: | Zinc difluoromethanesulfinate is a reagent widely used to incorporate difluoromethyl functionality onto biologically significant structural motifs. It is used to difluoromethylate compounds such as heteroarenes, thiols, enones, and α, β‐unsaturated carboxylic acids. |
| Other Notes: | Frequently Asked Questions are available for this Product. |
| Packaging: | 1 kg in glass bottle |
| Packaging: | 1, 10, 100 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 95% |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352103 |