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RuPhos Pd G3

ALDRICH/763403 - 98%

Synonym: (2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate; RuPhos-G3-Palladacycle; RuPhos-Pd-G3

CAS Number: 1445085-77-7
Empirical Formula (Hill Notation): C43H56NO5PPdS
Molecular Weight: 836.37
MDL Number: MFCD22572684
Linear Formula: C43H56NO5PPdS
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-763403-250MG 250 mg
 $91.10
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45-763403-1G 1 g
 $256.00
1/EA		 Add To Favorites
45-763403-5G 5 g
 $1030.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 763403-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 763403-5G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 763403-250MG

 

assay 98%
feature generation 3
form solid
functional group phosphine
InChI 1S/C30H43O2P.C12H10N.CH4O3S.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key AXZLIMCJMPNFFU-UHFFFAOYSA-M
mp 188-196 °C (decomposition)
Quality Level 100 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Cross Couplings
SMILES string CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC(C)Oc3cccc(OC(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6
Application: RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:• Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.
• Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.
• Suzuki-Miyaura-cross-coupling of aminothiophenes.
For small scale and high throughput uses, product is also available as ChemBeads (928283 )
General description: RuPhos Pd G3 is a third generation (G3)  Buchwald  precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
Packaging: 1, 5 g in glass bottle
Packaging: 250 mg in glass bottle
Purity 98%
mp 188-196 °C (decomposition)
UNSPSC 12161600

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