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XantPhos Pd G3

ALDRICH/763039 - 95%

Synonym: [(4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

CAS Number: 1445085-97-1
Empirical Formula (Hill Notation): C52H45NO4P2PdS
Molecular Weight: 948.35
MDL Number: MFCD22572675
Linear Formula: C52H45NO4P2PdS
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-763039-250MG 250 mg
 $58.10
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45-763039-1G 1 g
 $176.00
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45-763039-5G 5 g
 $728.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 763039-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 763039-250MG

 

assay 95%
feature generation 3
form solid
functional group phosphine
InChI 1S/C39H32OP2.C12H10N.CH4O3S.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h3-28H,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key AJVXPGQYAKUTGX-UHFFFAOYSA-M
mp 164-167 °C (decomposition)
Quality Level 100 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Cross Couplings
SMILES string CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC3(C)c4cccc(P(c5ccccc5)c6ccccc6)c4Oc7c(cccc37)P(c8ccccc8)c9ccccc9
Application: XantPhos Pd G3 may be used in the following processes:
• Negishi cross-coupling reaction during the synthesis of palmerolides.
• Aminocarbonylation of heteroaryl bromides with carbon monoxide (CO) in the presence of triethylamine.
• Coupling between polyglycosyl thiols and aglycon halides by C-S bond formation.
For small scale and high throughput uses, product is also available as ChemBeads (932213 )
General description: XantPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
Packaging: 1, 5 g in glass bottle
Packaging: 250 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 95%
mp 164-167 °C (decomposition)
UNSPSC 12161600

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