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(Trimethylphosphoranylidene)acetonitrile solution

ALDRICH/752940 - 0.5 M in THF

Synonym: CMMP; Cyanomethylenetrimethylphosphorane solution

CAS Number: 176325-83-0
Empirical Formula (Hill Notation): C5H10NP
Molecular Weight: 115.11
MDL Number: MFCD17013403
Linear Formula: C5H10NP
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-752940-5ML 5 mL
 $333.00
1/EA		 Add To Favorites
45-752940-10ML 10 mL
 $570.00
1/EA		 Add To Favorites

 

concentration 0.5 M in THF
density 0.896 g/mL at 25 °C
form liquid
functional group nitrile
  phosphine
InChI 1S/C5H10NP/c1-7(2,3)5-4-6/h5H,1-3H3
InChI key KJFJIEHJCVSAKJ-UHFFFAOYSA-N
Quality Level 100 
SMILES string CP(C)(C)=CC#N
storage temp. 2-8°C
General description: (Trimethylphosphoranylidene)acetonitrile is a reagent generally employed in the Wittig olefination of less reactive carboxylic acid compounds like esters, N-Boc lactams, lactones, and imides to give α,β-unsaturated nitriles. It is also used as an alternate reagent for Mitsonobu reaction by replacing DEAD/PPh3 for the alkylation of C-H and N-H bonds.
Other Notes: If precipitate is observed, warm gently to resolubilize
Packaging: 5, 10 mL in Sure/Seal™
Density 0.896 g/mL at 25 °C
Storage Temp. 2-8°C
UNSPSC 12352000

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