Advanced Search



[Ir(dtbbpy)(ppy)2]PF6

ALDRICH/747769

Synonym: [Ir(dtbbpy)(ppy)2][PF6]; Ir Photocatalyst; [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate

CAS Number: 676525-77-2
Empirical Formula (Hill Notation): C40H40F6IrN4P
Molecular Weight: 913.95
MDL Number: MFCD27952560
Linear Formula: C40H40F6IrN4P
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-747769-50MG 50 mg
 $119.00
1/EA		 Add To Favorites
45-747769-100MG 100 mg
 $226.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 747769-100MG
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 747769-50MG

 

form powder
InChI 1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
InChI key DZARMRZNOUWGQE-UHFFFAOYSA-N
photocatalyst activation 455 nm
Quality Level 100 
reaction suitability core: iridium
  reaction type: Photocatalysis
  reagent type: catalyst
SMILES string CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
storage temp. 2-8°C
Application: [Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:
• Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
• Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
• Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
• Aryl-alkyl C−C reductive cross-coupling reactions.
Product can be used with our line of photoreactors : Including Penn PhD (Z744035 ) & SynLED 2.0 (Z744080 )
Packaging: 50, 100 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Storage Temp. 2-8°C
UNSPSC 12161600

The following items have been added to your cart:

Choose a favorite list for this item:
Catalog Number Description Price
$

Returns/Order support

Please fill out the form below if you want to request order support from Krackeler Scientific.


Quick Order

* Required


New Year Price Updates

We are currently working diligently to update our website pricing information for the New Year. If you place an order, you will be acknowledged with any corrected pricing. If you'd like the most current information sooner, please don't hesitate to drop us an email or give us a call and we'd be happy to assist. Thank you for your patience while we are updating.

800-334-7725
office@krackeler.com


Play Video

To Request a Quote

  1. Search or Browse for items and add to them to your Shopping Cart.
  2. Click the "Request Quote" button at the bottom of the Shopping Cart page.
  3. Fill out required fields.
  4. Optionally you can convert to standard checkout mode by choosing a payment type.
  5. Click "Request Quote" at the bottom of the page.

You will be contacted with a quote.

To Order From a Quote

  1. Register and login to the website.
  2. Receive a quote from your sales representative or customer service.
  3. Have your copy of the quote in hand.
  4. Visit our quote module to search for your quote.
Back to Top