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Difluoromethyl 2-pyridyl sulfone

ALDRICH/746061 - 97% (HPLC)

Synonym: 2-[(Difluoromethyl)sulfonyl]pyridine; Hu Reagent; 2-(Difluoromethylsulfonyl)pyridine; 2-PySO2CF2H

CAS Number: 1219454-89-3
Empirical Formula (Hill Notation): C6H5F2NO2S
Molecular Weight: 193.17
MDL Number: MFCD17010193
Linear Formula: C6H5F2NO2S
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-746061-1G 1 g
 $141.00
1/EA		 Add To Favorites
45-746061-5G 5 g
 $663.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 746061-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 746061-5G

 

assay 97% (HPLC)
form solid
functional group fluoro
  sulfone
InChI 1S/C6H5F2NO2S/c7-6(8)12(10,11)5-3-1-2-4-9-5/h1-4,6H
InChI key YRQNSTAWTLXCEZ-UHFFFAOYSA-N
mp 44-49 °C
Quality Level 100 
SMILES string O=S(C1=CC=CC=N1)(C(F)F)=O
Application: Reagent is used in the olefination of ketones and aldehydes to form gem-difluoro olefins under basic conditions. Product is also used as a crucial intermediate toward making 1,1-difluorinated alkyl chains for the alkylation of heterocycles.
General description: Difluoromethyl 2-pyridyl sulfone (2-PySO2CF2H) is a reagent used in the gem-difluoroolefination of aldehydes and ketones. It is also used as a reagent in the nucleophilic difluoro(sulfonato)methylation of alcohols, N-sulfinyl imines, and halides.
Packaging: 1, 5 g in glass bottle
Purity 97% (HPLC)
mp 44-49 °C
UNSPSC 12352101

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