XPhos Pd G2

ALDRICH/741825 - 98%

Synonym: 2nd Generation XPhos Precatalyst; Chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II); X-Phos aminobiphenyl palladium chloride precatalyst; XPhos-Pd-G2

CAS Number: 1310584-14-5
Empirical Formula (Hill Notation): C₄₅H₅₉ClNPPd
Molecular Weight: 786.80
Linear Formula: C₄₅H₅₉ClNPPd
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-741825-250MG	250 mg	$0.00 1/EA CALL FOR PRICE	Add To Favorites
45-741825-1G	1 g	$147.00 1/EA	Add To Favorites
45-741825-5G	5 g	$523.00 1/EA	Add To Favorites
45-741825-10G	10 g	$1000.00 1/EA	Add To Favorites
45-741825-25G	25 g	$1940.00 1/EA	Add To Favorites
45-741825-100G	100 g	$6330.00 1/EA	Add To Favorites
45-741825-500G	500 g	$17780.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 741825-500G

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
feature	generation 2
form	solid
functional group	phosphine
InChI	1S/2C33H49P.2C12H10N.2ClH.2Pd/c1-23(2)27-21-31(24(3)4)33(32(22-27)25(5)6)26-14-13-19-30(20-26)34(28-15-9-7-10-16-28)29-17-11-8-12-18-29;1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;213-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;;;/h13-14,19-25,28-29H,7-12,15-18H2,1-6H3;13-14,19-25,27-28H,7-12,15-18H2,1-6H3;21-6,8-9H,13H2;21H;;/q;;;;;;2+1/p-2
InChI key	HMRJFNBZAWHTGN-UHFFFAOYSA-L
mp	202-210 °C
Quality Level	100
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
SMILES string	Nc1ccccc1-c2ccccc2[Pd]Cl.Nc3ccccc3-c4ccccc4[Pd]Cl.CC(C)c5cc(C(C)C)c(-c6cccc(c6)P(C7CCCCC7)C8CCCCC8)c(c5)C(C)C.CC(C)c9cc(C(C)C)c(c(c9)C(C)C)-c%10ccccc%10P(C%11CCCCC%11)C%12CCCCC%12

Application:	2nd Generation Buchwald Precatalysts • Widely used for Suzuki-Miyaura cross-coupling reactions
Application:	XPhos Pd G2 was employed as catalyst in the following reactions:• Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates. • Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids. • Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction. For small scale and high throughput uses, product is also available as ChemBeads (927775 )
General description:	XPhos Pd G2 is a bulky monodentate biaryl ligand. It is a Buchwald′s 2^nd generation preformed catalyst. It undergoes rapid reductive elimination to form a reactive, monoligated Pd(0) species.
Packaging:	1, 5, 10, 25, 100, 500 g in glass bottle
Packaging:	250 mg in glass bottle

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	98%
mp	202-210 °C
UNSPSC	12161600

To Order From a Quote