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1-Methyl-2-azaadamantane-N-oxyl

ALDRICH/738883 - 97%

Synonym: 1-Me-AZADO

CAS Number: 872598-44-2
Empirical Formula (Hill Notation): C10H16NO
Molecular Weight: 166.24
MDL Number: MFCD34679793
Linear Formula: C10H16NO
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-738883-25MG 25 mg
 $85.60
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45-738883-100MG 100 mg
 $293.00
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12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

 

assay 97%
form solid
greener alternative category Aligned ,  
greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry .
InChI 1S/C10H16NO/c1-10-5-7-2-8(6-10)4-9(3-7)11(10)12/h7-9H,2-6H2,1H3
InChI key IBNXYCCLPCGKDM-UHFFFAOYSA-N
mp 87-93 °C
Quality Level 100 
SMILES string CC12CC3CC(CC(C3)N1[O])C2
storage temp. 2-8°C
sustainability Greener Alternative Product
Application: 1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO) may be employed as catalyst for the aerobic oxidation of alcohols and sterically hindered alcohols.
Application: Catalytic oxidant for greener oxidation of alcohols under aerobic, solvent-free conditions. Recoverable and recyclable.

Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation 
General description: 1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO), a sterically less hindered nitroxyl radical, is widely used as catalyst. It is chemically stable and exhibits superior catalytic performance.
General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here .
Other Notes: 2-Azaadamantane N-Oxyl (AZADO) and 1-Me-AZADO: Highly Efficient Organocatalysts for Oxidation of Alcohols .
Packaging: 25, 100 mg in clear glass bottle
Risk Statements 52/53
Safety Statements 61
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 87-93 °C
Storage Temp. 2-8°C
UNSPSC 12352000

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