BrettPhos Pd G1, Methyl t-Butyl Ether Adduct

ALDRICH/718750 - may contain up to 1 mole equivalent of MTBE, 97%

Synonym: (BrettPhos) palladium(II) phenethylamine chloride; BrettPhos Palladacycle; BrettPhos precatalyst; Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2′,4′, 6′-triisopropyl-1,1′-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)

Empirical Formula (Hill Notation): C₄₃H₆₃ClNO₂PPd
Molecular Weight: 798.81
Linear Formula: C₄₃H₆₃ClNO₂PPd
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-718750-100MG	100 mg	$96.00 1/EA	Add To Favorites
45-718750-1G	1 g	$584.00 1/EA	Add To Favorites
45-718750-5G	5 g	$1580.00 1/EA	Add To Favorites

BrettPhos Palladacycle

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 718750-1G

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
feature	generation 1
form	solid
functional group	phosphine
InChI	1S/C35H53O2P.C8H10N.C5H12O.ClH.Pd/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28;9-7-6-8-4-2-1-3-5-8;1-5(2,3)6-4;;/h19-25,27-28H,9-18H2,1-8H3;1-4H,6-7,9H2;1-4H3;1H;/q;;;;+1/p-1
InChI key	OWHWOTGYDWMPCA-UHFFFAOYSA-M
mp	198-204 °C
Quality Level	100
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
SMILES string	COC(C)(C)C.NCCc1ccccc1[Pd]Cl.COc2ccc(OC)c(c2P(C3CCCCC3)C4CCCCC4)-c5c(cc(cc5C(C)C)C(C)C)C(C)C

Application:	Application Guide for Palladium Catalyzed Cross-Coupling Reactions Catalyst for: • C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines • Amination reaction • N-arylation of aminophenols
General description:	BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to −40 °C, and can be used in a variety of cross-coupling protocols.
Packaging:	1, 5 g in glass bottle
Packaging:	100 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P261 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
mp	198-204 °C
UNSPSC	12161600

To Order From a Quote