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Barium tert-butoxide

ALDRICH/715468 - 85%

Synonym: Barium di-t-butoxide

CAS Number: 24363-36-8
Empirical Formula (Hill Notation): C8H18BaO2
Molecular Weight: 283.55
MDL Number: MFCD00082644
Linear Formula: C8H18BaO2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-715468-1G 1 g
 $76.60
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 715468-1G

 

assay 85%
form powder
InChI 1S/2C4H9O.Ba/c2*1-4(2,3)5;/h2*1-3H3;/q2*-1;+2
InChI key SLPLCLDJTNLWPW-UHFFFAOYSA-N
mp >200 °C
Quality Level 100 
SMILES string CC(C)(C)O[Ba]OC(C)(C)C
storage temp. 2-8°C
Application: Barium tert-butoxide can be used:
• As a catalyst along with various phenolic ligands in the aldol reactions of amides with aldehydes and ketones.
• To prepare yttrium and copper metal complexes by reacting with Y(thd)3 and Cu(thd)2, where “thd” is 2,2,6,6-tetramethylheptane-3,5-dione.
• As an initiator along with an alkyl lithium in the butadiene copolymerization reaction.
• In the iridium catalyzed allylic alkylation of non-stabilized enolates.
General description: Barium tert-butoxide is a Brønsted base catalyst that can be used as a precursor of various barium catalysts like barium aryloxide. It can also be used in the preparation of barium diphenylmethanide, applicable in the organometallic chemistry.
Packaging: 1, 10 g in glass bottle
Purity 85%
mp >200 °C
Storage Temp. 2-8°C
UNSPSC 12352001

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