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(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer

ALDRICH/685062

Synonym: [Ir(OMe)(1,5-cod)]2; Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)

CAS Number: 12148-71-9
Empirical Formula (Hill Notation): C18H30Ir2O2
Molecular Weight: 662.86
MDL Number: MFCD08459360
Linear Formula: [Ir(OCH3)(C8H12)]2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-685062-250MG 250 mg
 $81.30
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45-685062-1G 1 g
 $224.00
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45-685062-25G 25 g
 $3920.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 685062-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 685062-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 685062-250MG

 

form crystals
InChI 1S/2C8H12.2CH3O.2Ir/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*+1;2*-1/b2*2-1-,8-7-;;;;
InChI key BGWIAAATAAWGOI-MIXQCLKLSA-N
mp 154-179 °C (D)
Quality Level 100 
reaction suitability core: iridium
  reagent type: catalyst
reaction type: C-H Activation
SMILES string C[O+]1[Ir-]2[O+](C)[Ir-]12.C3CC=CCCC=C3.C4CC=CCCC=C4
storage temp. −20°C
Application: A powerful C-H activation catalyst to prepare phenols from arenes
Application: Catalyst for:
• Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymerase
• Borylation/Suzuki-Miyaura coupling
• Metalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiaryls
• Tetraborylation reactions
• Highly regio- and enantioselective asymmetric hydroboration
• Ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation
Packaging: 1, 25 g in glass bottle
Packaging: 250 mg in glass bottle
mp 154-179 °C (D)
Storage Temp. −20°C
UNSPSC 12161600

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