Advanced Search



(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate

ALDRICH/683973 - 93%

Synonym: Bode Catalyst 2

CAS Number: 903571-02-8 (anhydrous)
Empirical Formula (Hill Notation): C21H22ClN3O · H2O
Molecular Weight: 385.89
MDL Number: MFCD20265585
Linear Formula: C21H22ClN3O · H2O
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-683973-100MG 100 mg
 $233.00
1/EA		 Add To Favorites
45-683973-250MG 250 mg
 $553.00
1/EA		 Add To Favorites

 

assay 93%
form solid
functional group ether
InChI 1S/C21H22N3O.ClH/c1-13-8-14(2)20(15(3)9-13)24-12-23-19(22-24)11-25-18-10-16-6-4-5-7-17(16)21(18)23;/h4-9,12,18,21H,10-11H2,1-3H3;1H/q+1;/p-1/t18-,21+;/m1./s1
InChI key GUECWMLEUCWYOS-WKOQGQMTSA-M
mp 226-230 °C
optical activity [α]20/D +158°, c = 1 in chloroform
Quality Level 100 
SMILES string [Cl-].Cc1cc(C)c(c(C)c1)-[n+]2c[n@@H]3[C@@H]4[C@@H](Cc5ccccc45)OCc3n2
Application: (5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate can be used as a catalyst:
• In the preparation of dihydropyridinones by reacting enals or α′-hydroxyenones with vinylogous amides via aza-Claisen annulations.
• In the oxidative coupling reactions of di(hetero)arylmethanes with enals to yield benzimidazole fused lactams.
• In the synthesis of organosilanes by reacting enals with β-silyl enones.
General description: It is an N-mesityl-substituted chiral triazolium N-heterocyclic carbene (NHC) compound. It was developed as an organocatalyst by the Bode group, for the catalytic generation of reactive species including activated carboxylates, homoenolates, and enolates.
Legal Information: Sold in collaboration with BioBlocks, Inc.
Packaging: 100 mg in clear glass bottle
Packaging: 250 mg in amber glass bottle
Purity 93%
mp 226-230 °C
UNSPSC 12352005

The following items have been added to your cart:

Choose a favorite list for this item:
Catalog Number Description Price
$

Returns/Order support

Please fill out the form below if you want to request order support from Krackeler Scientific.


Quick Order

* Required


New Tariffs & Effects on Pricing

Tariff note: As we navigate the current environment of tariff surcharges and mid-year manufacturer price increases, we want to keep you informed. While we have avoided making specific decisions thus far, we anticipate that we will be forced to implement a cost adjustment policy to offset the fees we have already been absorbing. We are committed to transparency and moderation in this process.

800-334-7725
office@krackeler.com


Play Video

To Request a Quote

  1. Search or Browse for items and add to them to your Shopping Cart.
  2. Click the "Request Quote" button at the bottom of the Shopping Cart page.
  3. Fill out required fields.
  4. Optionally you can convert to standard checkout mode by choosing a payment type.
  5. Click "Request Quote" at the bottom of the page.

You will be contacted with a quote.

To Order From a Quote

  1. Register and login to the website.
  2. Receive a quote from your sales representative or customer service.
  3. Have your copy of the quote in hand.
  4. Visit our quote module to search for your quote.
Back to Top