Bis(tert-butylcarbonyloxy)iodobenzene
ALDRICH/662283 - 97%
Synonym: (Di-tert-
CAS Number: 57357-20-7
Empirical Formula (Hill Notation): C16H23IO4
Molecular Weight: 406.26
MDL Number: MFCD08276835
Linear Formula: C16H23IO4
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 662283-5G
| assay | 97% |
| form | solid |
| functional group | iodo |
| InChI | 1S/C16H23IO4/c1-15(2,3)13 |
| InChI key | DZKPLZUSZXYHFB-UHFFFAOYSA |
| mp | 104-109 °C |
| Quality Level | 100  |
| reaction suitability | reagent type: catalyst reaction type: C-H Activation |
| reagent type: oxidant | |
| SMILES string | CC(C)(C)C(=O)O[I](OC(=O)C |
| Application: | Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination Reagent for: • Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation • Palladium-catalyzed diamination • Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization • Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins • C-H acyloxylation of arenes • Hypervalent iodine oxidant |
| Application: | Hypervalent iodine reagent used with the Rh2(esp)2 catalyst (662623) in the amination of C-H bonds. |
| Packaging: | 5, 25 g in glass bottle |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 104-109 °C |
| UNSPSC | 12352002 |