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1,10-Phenanthroline-5,6-dione

ALDRICH/496383 - 97%

Synonym: Stahl phd oxidant; phd

CAS Number: 27318-90-7
Empirical Formula (Hill Notation): C12H6N2O2
Molecular Weight: 210.19
MDL Number: MFCD00014473
Linear Formula: C12H6N2O2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-496383-1G 1 g
 $213.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 496383-1G

 

assay 97%
functional group ketone
InChI 1S/C12H6N2O2/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10/h1-6H
InChI key KCALAFIVPCAXJI-UHFFFAOYSA-N
mp 260 °C (dec.) (lit.)
Quality Level 200 
SMILES string O=C1C(=O)c2cccnc2-c3ncccc13
Application: 1,10-Phenanthroline-5,6-dione may be used in the preparation of homo- and heterometallic complexes with early transition metal ions.
Application: A Bifunctional quinone oxidant which, when used in conjunction with Zn2+ catalysts, is used to affect the aerobic oxidation of secondary amines to a variety of value added motifs, including indoles.

Bioinspired Aerobic Oxidation of Secondary Amines and Nitrogen Heterocycles with a Bifunctional Quinone Catalyst 
General description: 1,10-Phenanthroline-5,6-dione (phendio) forms Cu(II) and Ag(I) phendio complexes, which show potent anti-fungal and anti-cancer activity. The modification of glassy carbon (GC) electrodes with phendio complexes of transition metals leads to the catalytic oxidation of NADH at low overpotential.
Packaging: 1 g in glass bottle
Purity 97%
mp 260 °C (dec.) (lit.)
UNSPSC 12352100

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