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Silver trifluoromethanesulfonate

ALDRICH/483346 - ≥99.95% trace metals basis

Synonym: AgOTf; Silver triflate; Trifluoromethanesulfonic acid silver salt

CAS Number: 2923-28-6
Empirical Formula (Hill Notation): CAgF3O3S
Molecular Weight: 256.94
EC Number: 220-882-2
MDL Number: MFCD00013226
Linear Formula: CF3SO3Ag
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-483346-1G 1 g
 $78.20
1/EA		 Add To Favorites
45-483346-5G 5 g
 $169.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 483346-1G

 

assay ≥99.95% trace metals basis
InChI 1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChI key QRUBYZBWAOOHSV-UHFFFAOYSA-M
mp 286 °C (lit.)
Quality Level 100 
reaction suitability core: silver
  reagent type: catalyst
SMILES string [Ag+].[O-]S(=O)(=O)C(F)(F)F
Application: • Silver trifluoromethanesulfonate (AgOTf ) is a reactive triflating agent, which converts alkyl, acyl and sulfonyl halides to corresponding triflate species.
• It is a highly suitable electrophile to initiate acetylenic oxy-Cope rearrangement of substituted 5-hexen-1-yn-3-ols to synthesize corresponding α,δ-diethylenic aldehydes.
• It can also be used in the diastereoselective cyclization of amino ketenes where the diastereoselectivity depends on Ag(I) concentration.
Application: Gold Catalysts — 21st Century ′Gold Rush′ 
Packaging: 1 g in glass bottle
Packaging: 5 g in poly bottle
Purity ≥99.95% trace metals basis
mp 286 °C (lit.)
UNSPSC 12161600

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