rac-BINAP
ALDRICH/481084 - 97%
Synonym: (±)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene; 2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene; (±)-BINAP; [1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine]
CAS Number: 98327-87-8
Empirical Formula (Hill Notation): C44H32P2
Molecular Weight: 622.67
MDL Number: MFCD00010805
Linear Formula: [(C6H5)2PC10H6-]2
Product Type: Chemical
| assay | 97% |
| functional group | phosphine |
| InChI | 1S/C44H32P2/c1-5-19-35(20 |
| InChI key | MUALRAIOVNYAIW-UHFFFAOYSA |
| mp | 283-286 °C (lit.) |
| Quality Level | 200 ![]() |
| reaction suitability | reaction type: Cross Couplings |
| reagent type: ligand reaction type: Acylations |
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| reagent type: ligand reaction type: Arylations |
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| reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction |
|
| reagent type: ligand reaction type: C-C Bond Formation |
|
| reagent type: ligand reaction type: Decarboxylations |
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| reagent type: ligand reaction type: Stille Coupling |
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| SMILES string | P(c8ccccc8)(c7ccccc7)c1c( |
| Application: | Ligand employed in a palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines. Used with Cu (II) to catalyze addition of arylsulfonamides to styrenes and olefins. Amination of terpyridines with Pd catalysis. |
| General description: | Racemic version of BINAP. |
| Packaging: | 5, 25, 100, 500 g in glass bottle |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 283-286 °C (lit.) |
| UNSPSC | 12352005 |

