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Tris(dimethylamino)phosphine

ALDRICH/393290 - 97%

Synonym: (Me2N)3P; Hexamethyltriamidophosphite; Hexamethyltriaminophosphine; HMPT; Hexamethylphosphorous triamide

CAS Number: 1608-26-0
Empirical Formula (Hill Notation): C6H18N3P
Molecular Weight: 163.20
MDL Number: MFCD00008301
Linear Formula: P[N(CH3)2]3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-393290-5ML 5 mL
 $72.60
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45-393290-25ML 25 mL
 $297.00
1/EA		 Add To Favorites

 

assay 97%
bp 48-50 °C/12 mmHg (lit.)
density 0.898 g/mL at 25 °C (lit.)
form liquid
functional group phosphine
InChI 1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
InChI key XVDBWWRIXBMVJV-UHFFFAOYSA-N
Quality Level 100 
reaction suitability reagent type: ligand
reaction type: Reductions
  reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
reaction type: Wittig Reaction
refractive index n20/D 1.463 (lit.)
SMILES string CN(C)P(N(C)C)N(C)C
Application: Tris(dimethylamino)phosphine can be used a reagent in combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; for hydroxyl group activation; dehydrations.
Application: Tris(dimethylamino)phosphine can be used as a:
• Ligand in the preparation of arene-ruthenium(II) complex which is used as a catalyst in hydration of nitriles to amides.
• Phosphorus source along with InCl3 in the synthesis of InP colloidal quantum dots (QDs).
• Deoxygenating agent for some α-dicarbonyl compounds in the presence of fullerene C60.
Packaging: 5, 25 mL in glass bottle
Purity 97%
bp 48-50 °C/12 mmHg (lit.)
Density 0.898 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.463 (lit.)
UNSPSC 12161700

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