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Potassium diphenylphosphide solution

ALDRICH/380768 - 0.5 M in THF

Synonym: Potassium diphenylphosphine; Diphenylphosphine potassium salt; KPPh2

CAS Number: 15475-27-1
Empirical Formula (Hill Notation): C12H10KP
Molecular Weight: 224.28
MDL Number: MFCD00134530
Linear Formula: (C6H5)2PK
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-380768-100ML 100 mL
 $151.00
1/EA		 Add To Favorites
45-380768-800ML 800 mL
 $735.00
1/EA		 Add To Favorites

 

concentration 0.5 M in THF
density 0.929 g/mL at 25 °C
form liquid
functional group phosphine
InChI 1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
InChI key FCLYZQXPJKJTDR-UHFFFAOYSA-N
Quality Level 100 
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string [K]P(c1ccccc1)c2ccccc2
Application:

  • Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009 ).

  • Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007 ).

  • Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004 ).
Packaging: 100, 800 mL in Sure/Seal™
Density 0.929 g/mL at 25 °C
UNSPSC 12352002

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