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[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane

ALDRICH/379670

Synonym: Pd(dppf)Cl2 · CH2Cl2; Pd(dppf)Cl2 · DCM; [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1)

CAS Number: 95464-05-4
Empirical Formula (Hill Notation): C35H30Cl4FeP2Pd
Molecular Weight: 816.64
MDL Number: MFCD00792899
Linear Formula: C35H30Cl4FeP2Pd
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-379670-1G 1 g
 $66.30
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45-379670-5G 5 g
 $168.00
1/EA		 Add To Favorites
45-379670-25G 25 g
 $495.00
1/EA		 Add To Favorites
45-379670-250G 250 g
 $4750.00
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Pd(dppf)Cl2 · CH2Cl2
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 379670-250G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 379670-25G

 

form solid
InChI 1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-14H;1H2;2*1H;;/q;;;;;;+2/p-2
InChI key CWHRHCATIKFSND-UHFFFAOYSA-L
mp 275-280 °C
Quality Level 200 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Cross Couplings
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string [Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
Analysis Note: Catalyst employed in the borylation of aryl halides with Bis(pinacolato)diboron(473294) as well as the coupling of the derived arylboronic esters with aryl halides leading to biaryls. Also used in the synthesis of lactams by CO insertion and medium-ring aryl ethers by intramolecular coupling of an aryl halide with an alcohol.
Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions 
Packaging: 1, 5, 25, 250 g in glass bottle
mp 275-280 °C
UNSPSC 12161600

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