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Chlorobis(cyclooctene)iridium(I)dimer

ALDRICH/377155 - 97%

Synonym: [Ir(coe)2Cl]2; Di-μ-chlorotetrakis(cyclooctene)diiridium

CAS Number: 12246-51-4
Empirical Formula (Hill Notation): C32H56Cl2Ir2
Molecular Weight: 896.13
MDL Number: MFCD00213465
Linear Formula: C32H56Cl2Ir2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-377155-250MG 250 mg
 $158.00
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45-377155-1G 1 g
 $603.00
1/EA		 Add To Favorites
45-377155-5G 5 g
 $1970.00
1/EA		 Add To Favorites

 

assay 97%
form powder
InChI 1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChI key WBRREXQCZAFSKS-XFCUKONHSA-L
mp 160-165 °C (dec.) (lit.)
Quality Level 100 
reaction suitability core: iridium
  reagent type: catalyst
SMILES string Cl[Ir].Cl[Ir].[CH]1[CH]CCCCCC1.[CH]2[CH]CCCCCC2.[CH]3[CH]CCCCCC3.[CH]4[CH]CCCCCC4
Application: Catalyst for:
• Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand
• Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions
• Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions
• Alkylation reactions
• Guerbet reaction
• Allylic amination reactions in a DNA-diene-iridium(I) hybrid system
• Asymmetric hydroamination reactions
Application: Chlorobis(cyclooctene)iridium(I)dimer can be used as a catalyst for:
• Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand.
• Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions.
• Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions.
• Alkylation reactions.
• Guerbet reaction.
• Allylic amination reactions using a DNA-diene-iridium(I) hybrid system.
• Asymmetric hydroamination reactions.
Packaging: 1, 5 g in glass bottle
Packaging: 250 mg in glass bottle
Purity 97%
mp 160-165 °C (dec.) (lit.)
UNSPSC 12161600

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