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(1R,2R)-(−)-1,2-Diaminocyclohexane

ALDRICH/346721 - 98%

Synonym: (1R)-trans-1,2-Cyclohexanediamine

CAS Number: 20439-47-8
Empirical Formula (Hill Notation): C6H14N2
Molecular Weight: 114.19
MDL Number: MFCD00062985
Linear Formula: C6H10(NH2)2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-346721-1G 1 g
 $22.60
1/EA		 Add To Favorites
45-346721-5G 5 g
 $107.00
1/EA		 Add To Favorites

 

assay 98%
form solid
InChI 1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m1/s1
InChI key SSJXIUAHEKJCMH-PHDIDXHHSA-N
optical activity [α]20/D −25°, c = 5 in 1 M HCl
Quality Level 200 
SMILES string N[C@@H]1CCCC[C@H]1N
Application: (1R,2R)-(-)-1,2-Diaminocyclohexane may be used to prepare:
• Chiral C2-symmetric diphenylphosphoramide and diphenylthiophosphoramide ligands by reacting with diphenylphosphinic chloride and diphenylthiophosphinic chloride, respectively.
• Bis-urea and the amino-thiourea ligands by reacting with isocyanates and isothiocyanates, respectively.
• Biologically active chiral palladium(II) and platinum(II) complexes.
Application: Versatile ligand for the formation of metal complexes. Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis.
Packaging: 1, 5 g in glass bottle
Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
Symbol GHS05  GHS05
Signal word Danger
Hazard statements H314
Precautionary statements P280 - P305 + P351 + P338 - P310
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3259PSN1 8 / PGIII
WGK Germany WGK 3
Flash Point(F) 158.0 °F - closed cup
Flash Point(C) 70 °C - closed cup
Purity 98%
UNSPSC 12352116

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