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Tetrakis(acetonitrile)copper(I) hexafluorophosphate

ALDRICH/346276 - 97%

Synonym: Copper(I) tetrakis(acetonitrile) hexafluorophosphate; Cuprous tetrakis(acetonitrile) hexafluorophosphate

CAS Number: 64443-05-6
Empirical Formula (Hill Notation): C8H12CuF6N4P
Molecular Weight: 372.72
MDL Number: MFCD00064810
Linear Formula: [(CH3CN)4Cu]PF6
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-346276-5G 5 g
 $73.30
1/EA		 Add To Favorites
45-346276-25G 25 g
 $347.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 346276-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 346276-5G

 

assay 97%
form solid
InChI 1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1
InChI key GNQXUMGHBSAQBV-UHFFFAOYSA-N
mp 160 °C (dec.) (lit.)
Quality Level 100 
reaction suitability core: copper
  reagent type: catalyst
SMILES string [Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F
Application: Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:
• For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
• To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
• To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
• For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.
Packaging: 5, 25 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 160 °C (dec.) (lit.)
UNSPSC 12161600

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