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Di-n-butylmagnesium solution

ALDRICH/345113 - 1.0 M in heptane

Synonym: Bis-n-butylmagnesium; Dibutylmagnesium

CAS Number: 1191-47-5
Empirical Formula (Hill Notation): C8H18Mg
Molecular Weight: 138.53
MDL Number: MFCD00015225
Linear Formula: [CH3(CH2)3]2Mg
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-345113-100ML 100 mL
 $129.00
1/EA		 Add To Favorites
45-345113-800ML 800 mL
 $1010.00
1/EA		 Add To Favorites

 

concentration 1.0 M in heptane
density 0.713 g/mL at 25 °C
InChI 1S/2C4H9.Mg/c2*1-3-4-2;/h2*1,3-4H2,2H3;
InChI key ODHFJIDDBSDWNU-UHFFFAOYSA-N
Quality Level 100 
reaction suitability reaction type: Grignard Reaction
SMILES string CCCC[Mg]CCCC
Application: Di-n-butylmagnesium solution can be used as a reagent for the deprotection of aromatic and aliphatic benzyl thioethers to synthesize corresponding benzylthiols in the presence of titanocene dichloride. It can also be used as a catalyst to synthesize enantioenriched nitrogen-containing heterocyclic derivatives by the asymmetric ring-opening reaction of aziridines with substituted tetrazoles in the presence of chiral ligand.
General description: Di-n-butylmagnesium solution is a useful reagent for the synthesis of organomagnesium compounds.
Other Notes: • Contains up to 1 Wt% Triethylaluminum as a Viscosity Reducer
• This material can vary from light to very dark in appearance. These differences in color will have no effect on use.
• May contain up to 3% THF
Packaging: 100, 800 mL in Sure/Seal™
Symbol GHS02GHS05GHS07GHS08GHS09  GHS02,GHS05,GHS07,GHS08,GHS09
Signal word Danger
Hazard statements H225 - H250 - H260 - H304 - H314 - H336 - H410
Precautionary statements P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes F,C,N
Risk Statements 11-14/15-17-34-50/53-65-67
Safety Statements 26-36/37/39-43-45-61-62
RIDADR UN3399 - class 4.3 - PG 1 - EHS - Organometallic substance, liqu
WGK Germany WGK 2
Flash Point(F) 21.2 °F - closed cup
Flash Point(C) -6 °C - closed cup
Supplemental Hazard Statements EUH014
Density 0.713 g/mL at 25 °C
UNSPSC 12352103

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