(Trimethylsilyl)methylmagnesium chloride solution
ALDRICH/256021 - 1.0 M in diethyl ether
Synonym: (Trimethylsilyl)
CAS Number: 13170-43-9
Empirical Formula (Hill Notation): C4H11ClMgSi
Molecular Weight: 146.97
MDL Number: MFCD00009916
Linear Formula: (CH3)3SiCH2MgCl
Product Type: Chemical
| concentration | 1.0 M in diethyl ether |
| density | 0.777 g/mL at 25 °C |
| InChI | 1S/C4H11Si.ClH.Mg/c1-5(2, |
| InChI key | NAQATMJWCJCHOZ-UHFFFAOYSA |
| Quality Level | 100 ![]() |
| reaction suitability | reaction type: Grignard Reaction |
| SMILES string | C[Si](C)(C)C[Mg]Cl |
| Application: | Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides. |
| Packaging: | 100 mL in Sure/Seal™ |
| Symbol | ![]() ![]() GHS02,GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H225 - H302 - H314 - H336 |
| Precautionary statements | P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 |
| Hazard Codes | F,C |
| Risk Statements | 11-14-19-22-34-67 |
| Safety Statements | 16-26-36/37/39-45 |
| RIDADR | UN 3399A 4.3(3) / PGI |
| WGK Germany | WGK 3 |
| Flash Point(F) | -40.0 °F - closed cup |
| Flash Point(C) | -40 °C - closed cup |
| Supplemental Hazard Statements | EUH014 - EUH019 |
| Density | 0.777 g/mL at 25 °C |
| UNSPSC | 12352103 |




