Lithium tetrafluoroborate
ALDRICH/244767 - 98%
Synonym: Lithium borofluoride; Lithium fluoroborate
CAS Number: 14283-07-9
Empirical Formula (Hill Notation): BF4Li
Molecular Weight: 93.75
EC Number: 238-178-9
MDL Number: MFCD00011087
Linear Formula: LiBF4
Product Type: Chemical
| application(s) | battery precursors catalysts material synthesis precursor |
| assay | 98% |
| form | powder |
| greener alternative category | Enabling ![]() |
| greener alternative product characteristics | Design for Energy Efficiency Learn more about the Principles of Green Chemistry . |
| InChI | 1S/BF4.Li/c2-1(3,4)5;/q-1 |
| InChI key | UFXJWFBILHTTET-UHFFFAOYSA |
| mp | 293-300 °C (dec.) (lit.) |
| reaction suitability | core: lithium |
| SMILES string | [Li+].F[B-](F)(F)F |
| sustainability | Greener Alternative Product |
| Application: | Lithium tetrafluoroborate (LiBF₄) is used as an electrolyte salt in lithium-ion batteries. It contributes to the overall ionic conductivity of the electrolyte and helps in achieving better battery performance. LiBF₄ is used as an electrolyte additive in supercapacitors to enhance their performance, particularly in terms of energy density and charge-discharge cycles. It can be used as a catalyst in various chemical reactions. Its properties can help improve the efficiency and selectivity of catalytic processes. In a study, it was reported that lithium tetrafluoroborate can serve as an efficient catalyst for the intermolecular aza-Michael addition of aromatic amines to electron-deficient alkenes. The suitability of this catalyst for intramolecular aza-Michael addition, resulting in the formation of 2-aryl-2,3-dihydroquinoli |
| General description: | Lithium tetrafluoroborate (LiBF₄) is a versatile compound with significant applications in research, particularly in the fields of battery technology, solid-state batteries, supercapacitors, electrochemical sensors, catalysis, electrolyte development, polymer electrolytes, and environmental studies. We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here ![]() |
| Packaging: | 10, 50 g in glass bottle |
| Symbol | ![]() GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H302 - H314 |
| Precautionary statements | P260 - P280 - P301 + P312 + P330 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
| Hazard Codes | C |
| Risk Statements | 20/21/22-31-34 |
| Safety Statements | 22-26-27-36/37/39-45 |
| RIDADR | UN 3260 8 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 98% |
| mp | 293-300 °C (dec.) (lit.) |
| UNSPSC | 12352302 |



