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Isopropylmagnesium chloride solution

ALDRICH/230111 - 2.0 M in THF

Synonym: Chloro 1-methylethyl magnesium; Chloroisopropylmagnesium; Isopropylmagnesium chloride; iPrMgCl

CAS Number: 1068-55-9
Empirical Formula (Hill Notation): C3H7ClMg
Molecular Weight: 102.85
MDL Number: MFCD00000466
Linear Formula: (CH3)2CHMgCl
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-230111-4X25ML 25 mL
 $64.80
4/EA		 Add To Favorites
45-230111-100ML 100 mL
 $68.20
1/EA		 Add To Favorites
45-230111-4X100ML 100 mL
 $230.00
4/EA		 Add To Favorites
45-230111-800ML 800 mL
 $185.00
1/EA		 Add To Favorites
45-230111-2.5L 2.5 L
 $405.00
1/EA		 Add To Favorites
25 mL Sure/Seal™ Packaging

 

concentration 2.0 M in THF
density 0.975 g/mL at 25 °C
InChI 1S/C3H7.ClH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1
InChI key GPIBKUJXKCEZOH-UHFFFAOYSA-M
Quality Level 200 
reaction suitability reaction type: Grignard Reaction
SMILES string CC(C)[Mg]Cl
Application: Isopropylmagnesium chloride solution (2.0 M in THF) can be used as a reagent to synthesize:      
• 2,6-Diiodobenzaldehyde derivatives via regioselective metal-iodine exchange of 5-substituted 1,2,3-triiodobenzene in the presence of ethyl formate as a formylating agent.      
• Arene and heteroarene sulfonamides from aryl and heteroaryl bromides via the formation of corresponding Grignard reagents.
• Symmetrical pyridyl monoselenides by treating with bromo/iodopyridines followed by quenching with selenyl chloride, SeCl2.
General description: Isopropylmagnesium chloride is a highly reactive organomagnesium halide formed by the reaction of magnesium metal with isopropyl chloride. It is used in the Grignard reaction to form new carbon-carbon bonds.
Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging: 2.5 L in Sure/Seal™
Packaging: 4×25, 100, 4×100, 800 mL in Sure/Seal™
Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Density 0.975 g/mL at 25 °C
UNSPSC 12352103

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