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K-Selectride® solution

ALDRICH/220760 - 1.0 M potassium tri-sec-butylborohydride in THF

Synonym: Potassium tri-sec-butylborohydride solution

CAS Number: 54575-49-4
Empirical Formula (Hill Notation): C12H28BK
Molecular Weight: 222.26
MDL Number: MFCD00009324
Linear Formula: K[CH(CH3)CH2CH3]3BH
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-220760-100ML 100 mL
 $213.00
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45-220760-800ML 800 mL
 $913.00
1/EA		 Add To Favorites
25 mL Sure/Seal™ Packaging

 

concentration 1.0 M potassium tri-sec-butylborohydride in THF
density 0.913 g/mL at 25 °C
form liquid
InChI 1S/C12H28B.K/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
InChI key NHEDTYWJTOUTDG-UHFFFAOYSA-N
Quality Level 200 
reaction suitability reagent type: reductant
SMILES string [H][B]([K])(C(C)CC)(C(C)CC)C(C)CC
Application: • Reducing reagent

Reactant for:
• Preparation of a PCP-pincer palladium hydride-K-Selectride complex
• Formation of P-H, P-C, and C-H bonds by hydride attack
• Stereoselective conjugate hydride reduction reactions
Application: Stereoselective reducing agent for ketones. Hydride employed in regioselective reactions with transition metal ligands.
Legal Information: Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany
Packaging: 100, 800 mL in Sure/Seal™
Density 0.913 g/mL at 25 °C
UNSPSC 12352001

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