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Diisobutylaluminum hydride solution

ALDRICH/214981 - 1.0 M in THF

Synonym: DIBAL; DIBAL-H

CAS Number: 1191-15-7
Empirical Formula (Hill Notation): C8H19Al
Molecular Weight: 142.22
MDL Number: MFCD00008928
Linear Formula: [(CH3)2CHCH2]2AlH
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-214981-4X25ML 25 mL
 No Price  
45-214981-100ML 100 mL
 $78.70
1/EA		 Add To Favorites
45-214981-800ML 800 mL
 $298.00
1/EA		 Add To Favorites
45-214981-18L-KL 18 L
 $2230.00
1/EA		 Add To Favorites
25 mL Sure/Seal™ Packaging

 

bp 65 °C
concentration 1.0 M in THF
density 0.866 g/mL at 25 °C
form liquid
InChI 1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
InChI key AZWXAPCAJCYGIA-UHFFFAOYSA-N
Quality Level 200 
reaction suitability reagent type: reductant
SMILES string CC(C)C[AlH]CC(C)C
storage temp. 2-8°C
Application: Diisobutylaluminum hydride solution (1M in THF) is a powerful reducing agent. It can be used in the following reactions:
• Synthesis of trans-alkene isosteres of protected dipeptides.
• To generate bis(1,5-cyclooctadiene)nickel(0) (Ni(cod)2) in situ, which can catalyze the conjugate addition of ethenyltributyltin to 2-propenal to form tert-butyldimethyl[((E)-1,4pentadienyl)oxy]silane.
• Reduction of the arylpropiolate esters to give the corresponding propargyl alcohol.
Application: Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.
Packaging: 100, 800 mL in Sure/Seal™
Packaging: 18 L in Kilo-Lab™
Packaging: View returnable container options .
bp 65 °C
Density 0.866 g/mL at 25 °C
Storage Temp. 2-8°C
UNSPSC 12352001

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