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Palladium(II) acetylacetonate

ALDRICH/209015 - 99%

Synonym: Palladium(II) 2,4-pentanedionate; Pd(acac)2

CAS Number: 14024-61-4
Empirical Formula (Hill Notation): C10H14O4Pd
Molecular Weight: 304.64
EC Number: 237-859-8
MDL Number: MFCD00000025
Linear Formula: Pd(C5H7O2)2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-209015-1G 1 g
 $106.00
1/EA		 Add To Favorites
45-209015-5G 5 g
 $424.00
1/EA		 Add To Favorites
Pd(acac)2
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 209015-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 209015-5G

 

assay 99%
form powder
InChI 1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChI key JKDRQYIYVJVOPF-FDGPNNRMSA-L
mp 200-251 °C (dec.)
Quality Level 100 
reaction suitability core: aluminum
  reagent type: catalyst
SMILES string CC(=O)C=C(C)O[Pd]OC(C)=C/C(C)=O
Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions 
Application: Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:
• Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
• Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
• As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
General description: Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.
Packaging: 1, 5 g in glass bottle
Symbol GHS07  GHS07
Signal word Warning
Hazard statements H319
Precautionary statements P305 + P351 + P338
Hazard Codes Xi
Risk Statements 36
Safety Statements 26
RIDADR NONH for all modes of transport
WGK Germany WGK 2
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 99%
mp 200-251 °C (dec.)
UNSPSC 12352103

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