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Palladium(II) acetate

ALDRICH/205869 - reagent grade, 98%

Synonym: Pd(OAc)2; [Pd(OAc)2]3

CAS Number: 3375-31-3
Empirical Formula (Hill Notation): C4H6O4Pd
Molecular Weight: 224.51
EC Number: 222-164-4
MDL Number: MFCD00012453
Linear Formula: Pd(OCOCH3)2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-205869-1G 1 g
 $102.00
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45-205869-2G 2 g
 $204.00
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45-205869-10G 10 g
 $820.00
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45-205869-25G 25 g
 $1780.00
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45-205869-100G 100 g
 $6920.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 205869-100G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 205869-25G

 

assay 98%
form powder
grade reagent grade
InChI 1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
InChI key YJVFFLUZDVXJQI-UHFFFAOYSA-L
mp 216.3-223.7 °C (dec.)
Quality Level 200 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string CC(O[Pd]OC(C)=O)=O
Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions 
Application: [Pd(OAc)2]3 can be used as a:
• Catalyst for the regioselective anti-hydrochlorination of the terminal and internal alkynes.
• Precursor to prepare a heterogeneous palladium complex catalyst for the Heck-Coupling reaction and Sonogashira cross-coupling reaction.
General description: [Pd(OAc)2]3 is a palladium coordination complex and a heterogenous metal catalyst that is widely used in organic synthesis such as transmetalation, insertion, oxidative addition, direct homocoupling of aryl halides, Buchwald-Hartwig reaction of C-N bond formation, reduction of alkynes, and reductive elimination reactions. It is also employed as a starting material for the synthesis of other Pd(II) compounds as well as for the preparation of active palladium catalysts for Suzuki-Miyaura cross-coupling and C-H functionalization reactions.
Packaging: 1, 2, 10, 25, 100 g in glass bottle
Purity 98%
mp 216.3-223.7 °C (dec.)
UNSPSC 12161600

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