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tert-Butoxy bis(dimethylamino)methane

ALDRICH/20425 - technical

Synonym: Bredereck’s reagent

CAS Number: 5815-08-7
Empirical Formula (Hill Notation): C9H22N2O
Molecular Weight: 174.28
EC Number: 227-383-9
MDL Number: MFCD00042858
Linear Formula: (CH3)3COCH[N(CH3)2]2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-20425-10ML-F 10 mL
 $313.00
1/EA		 Add To Favorites
45-20425-50ML-F 50 mL
 $1390.00
1/EA		 Add To Favorites

 

bp 50-55 °C/15 mmHg (lit.)
density 0.844 g/mL at 25 °C (lit.)
functional group amine
  ether
grade technical
InChI 1S/C9H22N2O/c1-9(2,3)12-8(10(4)5)11(6)7/h8H,1-7H3
InChI key HXRAMSFGUAOAJR-UHFFFAOYSA-N
Quality Level 200 
refractive index n20/D 1.422
  n20/D 1.422 (lit.)
SMILES string CN(C)C(OC(C)(C)C)N(C)C
Analysis Note: mixture of tert-Butoxy bis(dimethylamino)methane, tris(dimethylamino)methane and N,N-Dimethylformamide di-tert-butyl acetal
Application: Reactant for:
• Preparation of pyrroloquinazolines as photochemotherapeutic agents
• Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition
• Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction
• Aminomethylenation reactions
Other Notes: Review; Mild condensation reactions
Packaging: 10, 50 mL in glass bottle
bp 50-55 °C/15 mmHg (lit.)
Density 0.844 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.422 (lit.); n20/D 1.422
UNSPSC 12352100

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