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Methylmagnesium bromide solution

ALDRICH/189898 - 3.0 M in diethyl ether

Synonym: Bromomethylmagnesium

CAS Number: 75-16-1
Empirical Formula (Hill Notation): CH3BrMg
Molecular Weight: 119.24
MDL Number: MFCD00000041
Linear Formula: CH3MgBr
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-189898-4X25ML 25 mL
 $53.00
4/EA		 Add To Favorites
45-189898-50ML 50 mL
 $55.50
1/EA		 Add To Favorites
45-189898-100ML 100 mL
 $105.00
1/EA		 Add To Favorites
45-189898-4X100ML 100 mL
 $521.00
4/EA		 Add To Favorites
45-189898-800ML 800 mL
 $476.00
1/EA		 Add To Favorites
45-189898-8L 8 L
 $2040.00
1/EA		 Add To Favorites
45-189898-18L-KL 18 L
 $3170.00
1/EA		 Add To Favorites
25 mL Sure/Seal™ Packaging

 

concentration 3.0 M in diethyl ether
density 1.035 g/mL at 25 °C
InChI 1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1
InChI key AVFUHBJCUUTGCD-UHFFFAOYSA-M
Quality Level 200 
reaction suitability reaction type: Grignard Reaction
SMILES string C[Mg]Br
Application: Methylmagnesium bromide solution (3M in diethyl ether) is used to synthesize:• 3S-(Boc-amino)-2,4-dimethyl-2-pentanol and methyl tert-butyl (S)-sulfoxide.
• Methyl potassium polyimide (K-PIM-1) (MeMgBr).
• 3(4R)-{3(2R,3S)-[4′-(1′-triphenylmethyl)imidazole]-2-bromo-1-oxobutyl)-4-phenyl2-oxazolidinone
• Benzyl 2-(2-oxopropyl)piperidine-1-carboxylate
• (R*, R*) 1-[1-(1-phenylethyl)pyrrolidin-2-yl]propan-2-one)
General description: Methylmagnesium bromide solution, also known as bromomethylmagnesium, is both a Lewis acid and nucleophile. It is commonly used as a grignard reagent in organic synthesis reactions.
Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging: 4×25, 50, 100, 4×100, 800 mL in Sure/Seal™
Packaging: 8, 18 L in Kilo-Lab™
Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Packaging: View returnable container options .
Density 1.035 g/mL at 25 °C
UNSPSC 12352111

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