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Super-Hydride® solution

ALDRICH/179728 - 1.0 M lithium triethylborohydride in THF

Synonym: Lithium triethylborohydride solution

CAS Number: 22560-16-3
Empirical Formula (Hill Notation): C6H16BLi
Molecular Weight: 105.94
MDL Number: MFCD00011703
Linear Formula: Li(C2H5)3BH
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-179728-4X25ML 25 mL
 No Price  
45-179728-100ML 100 mL
 $113.00
1/EA		 Add To Favorites
45-179728-800ML 800 mL
 $492.00
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45-179728-8L 8 L
 $2110.00
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25 mL Sure/Seal™ Packaging

 

concentration 1.0 M lithium triethylborohydride in THF
density 0.892 g/mL at 25 °C
form liquid
InChI 1S/C6H16B.Li/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1
InChI key WCJAYABJWDIZAJ-UHFFFAOYSA-N
Quality Level 200 
reaction suitability reagent type: reductant
SMILES string [Li+].[H][B-](CC)(CC)CC
Application: LiTEBH can be used as a reagent:
• To reduce alkyl halides to alkanes via dehydrogenation reactions.
• For the selective reduction of epoxides to Markovnikov alcohols.
• To reduce tosylates or mesylates primary alcohols to hydrocarbons.
• For reductive cyclization reactions for the preparation of useful intermediates.
• In the synthesis of hepta(manno-3-deoxy-6-O-t-butyldimethylsilyl)-β-cyclodextrin by reduction of hepta(manno-2,3-anhydro-6-O-t-butyldimethylsilyl)-β-cyclodextrin.
• For hydrodefluorination of C-F bonds using Ni catalyst.
• To prepare alkynyl alcohols from cleavage of cyclic keto-vinyl triflates.
• In the stereoselective reduction of bicyclic imides, isoquinolines, and pyridines.
• To prepare tungsten and molybdenum hydride complexes.
General description: Super-Hydride® solution (Lithium triethylborohydride or LiTEBH) is widely used as a powerful and selective reducing agent that shows super hydride activity in organic synthesis.
Legal Information: Super-Hydride is a registered trademark of Merck KGaA, Darmstadt, Germany
Packaging: 100, 800 mL in Sure/Seal™
Packaging: 2 L in Sure/Seal™
Packaging: 8, 18 L in Kilo-Lab™
Packaging: View returnable container options .
Density 0.892 g/mL at 25 °C
UNSPSC 12352302

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