Chloroform-d
ALDRICH/151831 - 99.8 atom % D, contains 1 % (v/v) TMS
Synonym: Deuterochloroform
CAS Number: 865-49-6
Empirical Formula (Hill Notation): CCl3D
Molecular Weight: 120.38
EC Number: 212-742-4
MDL Number: MFCD00000827
Linear Formula: CDCl3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 151831-100G.
| assay | 99% (CP) |
| bp | 60.9 °C (lit.) |
| contains | 1 % (v/v) TMS |
| density | 1.500 g/mL at 25 °C (lit.) |
| form | liquid |
| impurities | ≤0.0100% water water |
| InChI | 1S/CHCl3/c2-1(3)4/h1H/i1D |
| InChI key | HEDRZPFGACZZDS-MICDWDOJSA |
| isotopic purity | 99.8 atom % D |
| mass shift | M+1 |
| mp | −64 °C (lit.) |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | [2H]C(Cl)(Cl)Cl |
| technique(s) | NMR: suitable |
| Application: | Chloroform-d has been used as the deuterated solvent for the NMR spectral studies of the corresponding chiral derivatives of β-aminopropanoic acid containing the α-phenylethyl group, which serve as useful starting materials for the asymmetric synthesis of β-amino acids. |
| General description: | Chloroform-d (Deuterochloroform, CDCl3) is a deuterated derivative of chloroform. It contains 1%(v/v) TMS (Tetramethylsilane, added as a stabilizer). Quantitative infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν1 and ν2 bands of CHCl3 and CDCl3. |
| Packaging: | 50, 100, 250 g in glass bottle |
| Symbol |   GHS06,GHS08 |
| Signal word | Danger |
| Hazard statements | H302 - H315 - H319 - H331 - H336 - H351 - H361d - H372 |
| Precautionary statements | P202 - P301 + P312 - P302 + P352 - P304 + P340 + P311 - P305 + P351 + P338 - P308 + P313 |
| Hazard Codes | Xn |
| Risk Statements | 63-20/22-36/38-40-48/20 |
| Safety Statements | 36/37 |
| RIDADR | UN 1888 6.1 / PGIII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 99% (CP) |
| bp | 60.9 °C (lit.) |
| mp | −64 °C (lit.) |
| Density | 1.500 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12142201 |