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Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride

ALDRICH/14353 - ≥95.0%

Synonym: 5-Norbornene-2,3-dicarboxylic anhydride

CAS Number: 826-62-0
Empirical Formula (Hill Notation): C9H8O3
Molecular Weight: 164.16
EC Number: 212-557-9
MDL Number: MFCD00151106
Linear Formula: C9H8O3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-14353-250G 250 g
 $169.00
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assay ≥95.0%
InChI 1S/C9H8O3/c10-8-6-4-1-2-5(3-4)7(6)9(11)12-8/h1-2,4-7H,3H2/t4-,5+,6-,7+
InChI key KNDQHSIWLOJIGP-UMRXKNAASA-N
Quality Level 100 
SMILES string O=C1OC(=O)[C@H]2[C@@H]3C[C@@H](C=C3)[C@@H]12
solubility diethyl ether: 0.1 g/10 mL, clear, colorless
Application: • Sustainable chemical processes with Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride: Research by Kharitonov et al. (2012) explores synthetic transformations of higher terpenoids, employing Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride. Their work focuses on creating new cytotoxic agents, contributing to sustainable methodologies in organic synthesis (Kharitonov et al., 2012 ).
• Organic synthesis intermediate: Birchall et al. (2021) present a study on Himic Anhydride, utilizing a retro Diels-Alder reaction to demonstrate the application of Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride in teaching advanced organic laboratory techniques. This work includes an accompanying NMR study to further support the educational aspect of organic synthesis (Birchall et al., 2021 ).
General description: Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride reacts with methyl aminomethyllambertianate to give amide of bicyclo[2.2.1]heptan-1,2-dicarbocylic acid with a labdanoid substituent.
Packaging: 250 g in glass bottle
Purity ≥95.0%
UNSPSC 12352100

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