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Thianthrene

ALDRICH/122440 - 97%

Synonym: Dibenzodithiodioxane

CAS Number: 92-85-3
Empirical Formula (Hill Notation): C12H8S2
Molecular Weight: 216.32
EC Number: 202-197-0
MDL Number: MFCD00005065
Linear Formula: C12H8S2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-122440-25G 25 g
 $89.80
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assay 97%
bp 364-366 °C (lit.)
form solid
InChI 1S/C12H8S2/c1-2-6-10-9(5-1)13-11-7-3-4-8-12(11)14-10/h1-8H
InChI key GVIJJXMXTUZIOD-UHFFFAOYSA-N
mp 151-155 °C (lit.)
Quality Level 100 
SMILES string S1c2ccccc2Sc3ccccc13
solubility DMF: soluble
  H2O: insoluble
Application: Thianthrene has been used to study aqueous solubilities of several solid nitrogen-, sulfur- and oxygen-containing heterocyclic derivatives of anthracene, phenanthrene and fluorene. It has been used in determination of partition coefficients of several sulfur-containing aromatics in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and supercritical carbon dioxide.
General description: Thianthrene undergoes liquid phase tert-butylation in the presence of large pore zeolites and mesoporous aluminosilicates catalyst to yield tert-butyl derivatives. Thianthrene on oxidation in the presence of hydrogen peroxide and ligninase as catalyst from Phanerochaete chrysosporium yields thianthrene monosulfoxide.
Packaging: 25 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
bp 364-366 °C (lit.)
mp 151-155 °C (lit.)
UNSPSC 12352100

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