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Diethyl vinylphosphonate

ALDRICH/116130 - 97%

Synonym: Vinylphosphonic acid diethyl ester

CAS Number: 682-30-4
Empirical Formula (Hill Notation): C6H13O3P
Molecular Weight: 164.14
EC Number: 211-663-2
MDL Number: MFCD00009079
Linear Formula: CH2=CHPO(OCH2CH3)2
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-116130-10G 10 g
$165.00
1/EA
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45-116130-25G 25 g
$242.00
1/EA
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assay 97%
bp 202 °C (lit.)
density 1.068 g/mL at 25 °C (lit.)
functional group phosphonate
InChI 1S/C6H13O3P/c1-4-8-10(7,6-3)9-5-2/h6H,3-5H2,1-2H3
InChI key DREPONDJUKIQLX-UHFFFAOYSA-N
Quality Level 100 
refractive index n20/D 1.429 (lit.)
SMILES string CCOP(=O)(OCC)C=C
storage temp. 2-8°C
Application: Diethyl vinylphosphonate (DEVP) can be used as a precursor for the synthesis of:
• α, β-unsaturated phosphonates by reacting with arylboronic acids via Pd-catalyzed Mizoroki−Heck reaction.
• 2-(arylamino)ethyl phosphonates by condensing with primary and secondary amines via the aza-Michael addition reaction.

It can be also employed as a monomer unit for the preparation of high-molecular-weight polymer, poly(diethyl vinylphosphonate) using lanthanide complexes.{18)
Application: Diethyl vinylphosphonate has been used in the preparation of diethyl N-alkyl-2-aminoethylphosphonate.
Packaging: 10, 25 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) 230.0 °F - closed cup
Flash Point(C) 110 °C - closed cup
Purity 97%
bp 202 °C (lit.)
Density 1.068 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.429 (lit.)
Storage Temp. 2-8°C
UNSPSC 12352100

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