Methyl thioglycolate
ALDRICH/108995 - 95%
Synonym: Methyl mercaptoacetate
CAS Number: 2365-48-2
Empirical Formula (Hill Notation): C3H6O2S
Molecular Weight: 106.14
EC Number: 219-121-7
MDL Number: MFCD00004873
Linear Formula: HSCH2CO2CH3
Product Type: Chemical
| assay | 95% |
| bp | 42-43 °C/10 mmHg (lit.) |
| density | 1.187 g/mL at 25 °C (lit.) |
| InChI | 1S/C3H6O2S/c1-5-3(4)2-6/h |
| InChI key | MKIJJIMOAABWGF-UHFFFAOYSA |
| Quality Level | 200  |
| reaction suitability | reaction type: Photocatalysis |
| reagent type: catalyst | |
| reagent type: ligand reaction type: [1,2]-Wittig Rearrangement |
|
| refractive index | n |
| SMILES string | COC(=O)CS |
| Application: | Methyl thioglycolate was used in the preparation of: • 3-carbomethoxy-4- oxotetrahydrothiopyran, 2- and 4-carbomethoxy-3-oxotetra • methyl thioglycolate and aminoethanethiol conjugated gold nanorods. Thiol Organocatalyst used in conjunction with visible light photocatalysis to affect the direct arylation of benzylic ether C-H bonds A General Strategy for Organocatalytic Activation of C–H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers  |
| General description: | Methyl thioglycolate reacts with nonprotein component of the antitumor antibiotic neocarzinostatin to form 1:1 adduct. It reacts with isothiocyanate to form Rhodanine. |
| Packaging: | 5, 100, 500 g in glass bottle |
| Symbol |   GHS02,GHS06 |
| Signal word | Danger |
| Hazard statements | H226 - H301 - H315 - H319 - H332 - H335 |
| Precautionary statements | P210 - P233 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338 |
| Hazard Codes | Xn |
| Risk Statements | 10-20/22-36/37/38 |
| Safety Statements | 26-36/37 |
| RIDADR | UN 1992 6.1(3) / PGIII |
| WGK Germany | WGK 1 |
| Flash Point(F) | 132.8 °F - closed cup |
| Flash Point(C) | 56 °C - closed cup |
| Purity | 95% |
| bp | 42-43 °C/10 mmHg (lit.) |
| Density | 1.187 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |