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2,2,2-Trifluoroacetophenone

ALDRICH/107840 - 99%

Synonym: α,α,α-Trifluoroacetophenone; Phenyl trifluoromethyl ketone

CAS Number: 434-45-7
Empirical Formula (Hill Notation): C8H5F3O
Molecular Weight: 174.12
EC Number: 207-103-1
MDL Number: MFCD00000420
Linear Formula: CF3COC6H5
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-107840-5G 5 g
 $54.70
1/EA		 Add To Favorites
45-107840-25G 25 g
 $260.00
1/EA		 Add To Favorites
45-107840-100G 100 g
 $567.00
1/EA		 Add To Favorites

 

assay 99%
bp 165-166 °C (lit.)
  46-48 °C/14 mmHg (lit.)
density 1.24 g/mL at 25 °C (lit.)
functional group fluoro
  ketone
  phenyl
InChI 1S/C8H5F3O/c9-8(10,11)7(12)6-4-2-1-3-5-6/h1-5H
InChI key KZJRKRQSDZGHEC-UHFFFAOYSA-N
Quality Level 200 
refractive index n20/D 1.458 (lit.)
SMILES string FC(F)(F)C(=O)c1ccccc1
Application: 2,2,2-Trifluoroacetophenone was used in the synthesis of new fluorinated polymers, having high average molecular weight, high thermal stability and good film-forming properties.
General description: 2,2,2-Trifluoroacetophenone is the starting material for the synthesis of f 3-trifluoromethyl-3-phenyldiazirine. It undergoes asymmetric reduction with optically active Grignard reagent to form 2,2,2-trifluoro-1-phenylethanol. It undergoes condensation with biphenyl, terphenyl, a mixture of biphenyl with terphenyl, phenyl ether and diphenoxybenzophenone to form new aromatic 3F polymers.

2,2,2-trifluoroacetophenone is used as an organocatalyst for the oxidation of tertiary amines and azines to N-oxidesalkenes.
Packaging: 5, 25, 100 g in glass bottle
Purity 99%
bp 165-166 °C (lit.); 46-48 °C/14 mmHg (lit.)
Density 1.24 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.458 (lit.)
UNSPSC 12352100

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