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Dichlorophenylborane

ALDRICH/101346 - 97%

Synonym: NSC 93889; Phenylboron dichloride; Phenyldichloroborane

CAS Number: 873-51-8
Empirical Formula (Hill Notation): C6H5BCl2
Molecular Weight: 158.82
MDL Number: MFCD00013612
Linear Formula: C6H5BCl2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-101346-1G 1 g
 $54.90
1/EA		 Add To Favorites
45-101346-5G 5 g
 $121.00
1/EA		 Add To Favorites
45-101346-25G 25 g
 $308.00
1/EA		 Add To Favorites

 

assay 97%
bp 66 °C/11 mmHg (lit.)
density 1.224 g/mL at 25 °C (lit.)
InChI 1S/C6H5BCl2/c8-7(9)6-4-2-1-3-5-6/h1-5H
InChI key NCQDQONETMHUMY-UHFFFAOYSA-N
Quality Level 100 
reaction suitability reagent type: reductant
refractive index n20/D 1.545 (lit.)
SMILES string ClB(Cl)c1ccccc1
Application: Catalyst for:
• Antiproliferative macrolide and cell migration inhibitor lactimidomycin
• Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions
• Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives
• Stereoselective alkylative ring opening of cyclic anhydrides
• Cross-metathesis reaction of amino derivatives with olefins
• Asymmetric acetate aldol reactions
• The reaction of aryl aldehydes with styrene and (E)-β-methylstyrene
Application: Dichlorophenylborane can be used as a catalyst for:
• The synthesis of an antiproliferative macrolide and cell migration inhibitor lactimidomycin.
• Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions.
• Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives.
• Stereoselective alkylative ring opening of cyclic anhydrides.
• Cross-metathesis reaction of amino derivatives with olefins.
• Asymmetric acetate aldol reactions.
Packaging: 1, 5, 25 g in glass bottle
Purity 97%
bp 66 °C/11 mmHg (lit.)
Density 1.224 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.545 (lit.)
UNSPSC 12352002

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